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Curriculum | B.Sc (Non- Medical) | Paper I : (Theory) Organic Chemistry Code- 09010209

Curriculum

Paper I : (Theory) Organic Chemistry

 Code- 09010209

S. No / Section Topic Learning Objective (At the end of the session the students should be able to) Teaching Guidelines Methodology Hours
A

 

 Alkenes :

1.       Nomenclature of alkenes, , mechanisms of dehydration of alcohols and  dehydro halogenation  of  alkyl  halides,.

2.       The  Saytzeff  rule, Hofmann elimination, physical properties and relative stabilities of alkenes.

3.       Chemical   reactions   of   alkenes,  mechanisms   involved   in hydrogenation,     electrophilic     and     free radical additions,

4.        Markownikoff’s   rule,   hydroboration–oxidation,   oxy mercuration- reduction, ozonolysis, hydration, hydroxylation and oxidation with KMnO4

 At the end of the training / teaching students must be able to reprduce nomenclature of alkenes, The  Saytzeff  rule, Hofmann elimination, Markownikoff’s   rule physical and chemical  pro- perties of alkene. To cover the nomenclature of alkenes. To explain mechanisms of dehydration of alcohols and  dehydro halogenation  of  alkyl  halides , electrophilic and free radical addition. To cover  Saytzeff  rule, Hofmann elimination, Markownikoff’s   rule,   hydroboration–oxidation,   oxy mercuration- reduction, ozonolysis, hydration, hydroxylation and oxidation with KMnO4 along with examples. White Board- Marker Pen. PBL, SIS, Tutorials, Video, Audio, Models, Lab Visits, Teacher Seminar 10
 

B

 

 Arenes and Aromaticity :

1.       Nomenclature of benzene derivatives:. Aromatic nucleus and side chain.

2.       Aromaticity:the Huckel rule, aromatic ions, annulenes up to 10 carbon  atoms,  aromatic,  anti  –  aromatic  and  non  –  aromatic compounds.

3.       Aromatic electrophilic substitution  , general pattern   of   the mechanism,  mechansim  of  nitration, halogenation,  sulphonation, and  Friedel-Crafts reaction. Energy profile diagrams.

4.       Activating, deactivating  substituents and orientation

 At the end of the training / teaching students must be able to reprduce nomenclature of benzene  derivatives , Huckel rule , Aromatic electrophilic substitution  , Activating, deactivating  substituents and orientation

 

  To cover  nomenclature of benzene derivatives , aromaticity  (Huckel rules up to 10 carbon atoms). To explain mechanism of electrophilic substitution including ,  mechansim  of  nitration, halogenation,  sulphonation, and  Friedel-Crafts reaction etc.  To cover Activating, deactivating  substituents and orientation with number of examples.

 

 White Board- Marker Pen, PBL, SIS, Tutorials, Video, Audio, Models, Lab Visits, Teacher Seminar 10
 

C

 

 

 Dienes and Alkynes :

1.   Nomenclature and classification of dienes isolated, conjugated and cumulated dienes.

2.   Structure of butadiene,. Chemical reactions, 1,2 and 1,4 additions (Electrophilic & free radical mechanism),Diels-Alder  reaction,

3.   3. Nomenclature,  structure  and  bonding  in alkynes. Methods of formation.  Chemical reactions of alkynes, acidity of alkynes.

4.   Mechanism of electrophilic and nucleophilic addition  reactions, hydroboration-oxidation of alkynes

Alkyl and Aryl Halides :

1.       Nomenclature and classes of alkyl halides, methods of formation, chemical     reactions.

2.        Mechanisms  and  stereochemistry  of nucleophilic substitution reactions of alkyl  halides,  SN2 and  SN1 reactions with energy profile diagrams. Methods of formation and reactions of aryl halides,

3.       The addition- elimination     and     the   elimination- addition     mechanisms     of  n ucleophilic aromatic substitution reactions.

4.        Relative reactivities of alkyl halides vsallyl, vinyl and arylhalides

 At the end of the training / teaching students must be able to reproduce  nomenclature and classification of dienes isolated, conjugated and cumulated dienes, alkynes , alkyl halides and Aryl Halides. At the end of the training / teaching students must be able to demo At the end of the training / teaching students must be able to demonstrate  chemical and physical propertieees including the mecs including the mechanism of the dienes isolated, conjugated and cumulated dienes, alkynes , alkyl halides and Aryl Halides. To cover nomenclature of  Dienes and Alkynes, Alkyl and Aryl Halides with examples.  To explain Structure of butadiene,. Chemical reactions, 1,2 and 1,4 additions (Electrophilic & free radical mechanism),Diels-Alder  reaction.

 

To cover structure  and  bonding  in alkynes. Methods of formation.  Chemical reactions of alkynes, acidity of alkynes. Mechanism of electrophilic and nucleophilic addition  reactions, hydroboration-oxidation of alkynes.

 

To explain methods of preparation of alkyl and aryl halides . To cover Mechanisms  and  stereochemistry  of nucleophilic substitution reactions of alkyl  halides,  SN2 and  SN1 reactions with energy profile diagrams. Methods of formation and reactions of aryl halides along with examples.

The addition- elimination     and     the   elimination- addition     mechanisms     of  n ucleophilic aromatic substitution reactions.

Relative reactivities of alkyl halides vsallyl, vinyl and arylhalides along with examples.

 White Board- Marker Pen ,PBL, SIS, Tutorials, Video, Audio, Models, Lab Visits, Teacher Seminar 16