Curriculum
Paper I : (Theory) Organic Chemistry
Code- 09010209
S. No / Section | Topic | Learning Objective (At the end of the session the students should be able to) | Teaching Guidelines | Methodology | Hours |
A
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Alkenes :
1. Nomenclature of alkenes, , mechanisms of dehydration of alcohols and dehydro halogenation of alkyl halides,. 2. The Saytzeff rule, Hofmann elimination, physical properties and relative stabilities of alkenes. 3. Chemical reactions of alkenes, mechanisms involved in hydrogenation, electrophilic and free radical additions, 4. Markownikoff’s rule, hydroboration–oxidation, oxy mercuration- reduction, ozonolysis, hydration, hydroxylation and oxidation with KMnO4 |
At the end of the training / teaching students must be able to reprduce nomenclature of alkenes, The Saytzeff rule, Hofmann elimination, Markownikoff’s rule physical and chemical pro- perties of alkene. | To cover the nomenclature of alkenes. To explain mechanisms of dehydration of alcohols and dehydro halogenation of alkyl halides , electrophilic and free radical addition. To cover Saytzeff rule, Hofmann elimination, Markownikoff’s rule, hydroboration–oxidation, oxy mercuration- reduction, ozonolysis, hydration, hydroxylation and oxidation with KMnO4 along with examples. | White Board- Marker Pen. PBL, SIS, Tutorials, Video, Audio, Models, Lab Visits, Teacher Seminar | 10 |
B
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Arenes and Aromaticity :
1. Nomenclature of benzene derivatives:. Aromatic nucleus and side chain. 2. Aromaticity:the Huckel rule, aromatic ions, annulenes up to 10 carbon atoms, aromatic, anti – aromatic and non – aromatic compounds. 3. Aromatic electrophilic substitution , general pattern of the mechanism, mechansim of nitration, halogenation, sulphonation, and Friedel-Crafts reaction. Energy profile diagrams. 4. Activating, deactivating substituents and orientation |
At the end of the training / teaching students must be able to reprduce nomenclature of benzene derivatives , Huckel rule , Aromatic electrophilic substitution , Activating, deactivating substituents and orientation
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To cover nomenclature of benzene derivatives , aromaticity (Huckel rules up to 10 carbon atoms). To explain mechanism of electrophilic substitution including , mechansim of nitration, halogenation, sulphonation, and Friedel-Crafts reaction etc. To cover Activating, deactivating substituents and orientation with number of examples.
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White Board- Marker Pen, PBL, SIS, Tutorials, Video, Audio, Models, Lab Visits, Teacher Seminar | 10 |
C
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Dienes and Alkynes :
1. Nomenclature and classification of dienes isolated, conjugated and cumulated dienes. 2. Structure of butadiene,. Chemical reactions, 1,2 and 1,4 additions (Electrophilic & free radical mechanism),Diels-Alder reaction, 3. 3. Nomenclature, structure and bonding in alkynes. Methods of formation. Chemical reactions of alkynes, acidity of alkynes. 4. Mechanism of electrophilic and nucleophilic addition reactions, hydroboration-oxidation of alkynes Alkyl and Aryl Halides : 1. Nomenclature and classes of alkyl halides, methods of formation, chemical reactions. 2. Mechanisms and stereochemistry of nucleophilic substitution reactions of alkyl halides, SN2 and SN1 reactions with energy profile diagrams. Methods of formation and reactions of aryl halides, 3. The addition- elimination and the elimination- addition mechanisms of n ucleophilic aromatic substitution reactions. 4. Relative reactivities of alkyl halides vsallyl, vinyl and arylhalides |
At the end of the training / teaching students must be able to reproduce nomenclature and classification of dienes isolated, conjugated and cumulated dienes, alkynes , alkyl halides and Aryl Halides. At the end of the training / teaching students must be able to demo At the end of the training / teaching students must be able to demonstrate chemical and physical propertieees including the mecs including the mechanism of the dienes isolated, conjugated and cumulated dienes, alkynes , alkyl halides and Aryl Halides. | To cover nomenclature of Dienes and Alkynes, Alkyl and Aryl Halides with examples. To explain Structure of butadiene,. Chemical reactions, 1,2 and 1,4 additions (Electrophilic & free radical mechanism),Diels-Alder reaction.
To cover structure and bonding in alkynes. Methods of formation. Chemical reactions of alkynes, acidity of alkynes. Mechanism of electrophilic and nucleophilic addition reactions, hydroboration-oxidation of alkynes.
To explain methods of preparation of alkyl and aryl halides . To cover Mechanisms and stereochemistry of nucleophilic substitution reactions of alkyl halides, SN2 and SN1 reactions with energy profile diagrams. Methods of formation and reactions of aryl halides along with examples. The addition- elimination and the elimination- addition mechanisms of n ucleophilic aromatic substitution reactions. Relative reactivities of alkyl halides vsallyl, vinyl and arylhalides along with examples. |
White Board- Marker Pen ,PBL, SIS, Tutorials, Video, Audio, Models, Lab Visits, Teacher Seminar | 16 |