#### CHEMISTRY – I

#### Code – 09050105

S.No. |
Content of the topics |
Learning Objectives |
Teaching Guidelines |
Methodology |
Time (Hours) |

1 | · Atomic Structure: Idea of de Broglie matter waves, Heisenberg uncertainty principle, atomic orbital’s, quantum numbers, radial and angular wave functions and probability distribution curves, shapes of s, p, d orbitals. Aufbau and Pauli exclusion principles, Hund’s multiplicity rule, Electronic configurations of the elements, effective nuclear charge, Slater’s rules.
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Student will be able to study limit, Continuity & differentiability of function | Lecture should be effective so that student will be able to grasp the topics easily | Assignment/ seminar/ Class tests/ Presentation | 14 |

2 | · Gaseous States: Maxwell’s distribution o f velocities and energies (derivation excluded)
· Calculation of root mean square velocity, average velocity and most probable velocity. Collis ion diameter, collision number, collision frequency and mean free path. Deviation of Real gases from ideal behaviour. Derivation of Vander Waal’s Equation of State, its application in the calculation of Boyle’s temperature (compression factor). Explanation of behaviour of real gases using Vander Waal’s equation. Critical Phenomenon: Critical temperature, Critical pressure, critical volume and their determination. PV isotherms of real gases, continuity of states, the isotherms of Vander Waal’s equation, relationship between critical constants and Vander Waal’s constants. Critical compressibility factor. The Law of corresponding states. Liquefaction of gases. · · |
Student will be able to study of Asymptotes, Curvature and Points of infixion | Lecture should be effective so that student will be able to grasp the topics easily | Assignment/ seminar/ Class tests/ Presentation | 15 |

3 |
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Student will be able to trace the curves & study Reduction formulae , Rectification | Lecture should be effective so that student will be able to grasp the topics easily | Assignment/ seminar/ Class tests/ Presentation | 8 |

4 | · Mechanism of Organic Reactions: Curved arrow notation, drawing electron movements with arrows, half-headed and double-headed arrows, homolytic and heterolytic bond breaking. Types of reagents electrophiles and nucleophiles. Types of organic reactions. Reactive intermediates carbocations, carbanions, free radicals, |
Student will be able to find the area and Volumes of curves | Lecture should be effective so that student will be able to grasp the topics easily | Assignment/ seminar/ Class tests/ Presentation | 8 |

Books Recommended:

- Atkins, P. W. & Paula, J. de Atkin’s Physical Chemistry 8 th Ed., Oxford University Press (2006)
- Castellan, G. W. Physical Chemistry 4 th Ed. Narosa (2004).
- Lee, J.D. Concise Inorganic Chemistry, ELBS, 1991.
- Finar, I. L. Organic Chemistry (Volume 1), Dorling Kindersley (India) Pvt. Ltd. (PE).
- Eliel, E. L. & Wilen, S. H. Stereochemistry of Organic Compounds; Wiley: London, 1994.