| S.N/Unit |
Topic |
Learning Objectives |
Teaching guidelines |
Methodology |
Time (Hours) |
| 1 |
Study of Vibrational Spectroscopy |
Symmetry and shapes of AB2, AB3,AB4.AB5 and AB6 |
To cover symmetry and shapes of AB2, AB3, AB4, AB5 and AB6; Modes of bonding of ambidentate ligands- Ethylenediamine and diketonate complexes; Application of resonance Raman Spectroscopy particularly for the study of active sites of metalloproteins as myoglobin and haemoglobin |
Presentation |
15 |
| Modes of bonding of ambidentate ligands- Ethylenediamine and diketonate complexes |
Presentation |
| Application of resonance Raman Spectroscopy particularly for the study of active sites of metalloproteins as myoglobin and haemoglobin |
Presentation |
| 2 |
Study of Electron Spin Resonance Spectroscopy |
The Principle |
To cover the principle of Electron Spin Resonance; presentation of the spectrum; hyperfine coupling and hyperfine splitting in various structures; factors affecting magnitude of g; zero field splitting and Kramer’s degeneracy;applications to transition metal complexes having one and more than one unpaired electron; applications to inorganic free radicals; study of electron exchange reactions |
Conventional |
15 |
| Presentation of the spectrum |
Presentation |
| Hyperfine coupling and hyperfine splitting in various structures |
Presentation |
| Factors affecting magnitude of g |
Conventional |
| Zero field splitting and Kramer’s degeneracy |
Presentation |
| Applications to transition metal complexes having one and more than one unpaired electron |
Presentation |
| Applications to inorganic free radicals |
Presentation |
| Study of electron exchange reactions. |
Conventional |
| 3 |
Study of Moessbauer Spectroscopy |
Basic principles |
To cover basic principles, spectral display and isomer shift; factors affecting magnitude of isomer shift; quadrupole and magnetic hyperfine splitting; applications for techniques to study structure and bonding of Fe and Sn compounds; detection of oxidation states and nature of M-L bond |
Conventional |
8 |
| Spectral display and isomer shift |
Presentation |
| Factors affecting the magnitude of isomer shift |
Conventional |
| Quadrupole and magnetic hyperfine interaction |
Presentation |
| The applications for techniques to study bonding and structure of Fe2+, Fe3+ ; Sn2+ and Sn4+ compounds. |
Presentation |
| Detection of oxidation states and nature of M-L bond. |
Presentation |
| Study of Mass spectrometry |
Principle and representation |
To cover principle and representation; interactions of molecule with high energy electrons; interpretation of mass spectrum and effect of isotopes on appearance of mass spectrum; applications |
Conventional |
7 |
| Interaction of molecule with high energy electrons |
Presentation |
| Interpretation of mass spectrum and effect of isotopes on appearance of mass spectrum. |
Presentation |
| Applications- finger print application,molelcular weight determination |
Presentation |
| Heat of sublimation of high melting solids. |
Conventional |
| 4 |
Study of Nuclear Magnetic Resonance Spectroscopy |
Chemical shifts and coupling constants of 19F and 31P NMR spectra |
To cover chemical shifts and coupling constants of 19F and 31P NMR spectra; 19F spectra of fluoroacetone,1-bromo-1-Fluoroethane, dimethyl phosphorus trifluoride and bromine pentafluoride;31P spectra of HPF2 HPO(OH)2 H2 PO(OH), cis- Pt(Pet3)2 Cl2; 31P NMR for structural determination of Complexes with phosphorus ligands.E50 |
Presentation |
7 |
| 19F Spectra of fluoroacetone, 1-bromo-1-Fluoroethane, dimethyl phosphorus trifluoride and bromine pentafluoride |
Presentation |
| 31P spectra of HPF2 HPO(OH)2 H2 PO(OH), cis- Pt(Pet3)2 Cl2 |
Presentation |
| 31P NMR for structural determination of Complexes with phosphorus ligands.E50 |
Presentation |
| Spectra of Paramagnetic Materials |
Contact shift, its origin and application |
To cover contact shift, its origin and application; pseudo contact shift of diamagnetic complexes; spectra of free radicals and Lanthanide shift reagents; magnetic susceptibility measurement; solid state NMR- wide line NMR; magic angle spinning and applications of magnetic resonance imaging. |
Presentation |
4 |
| Pseudo contact shift of Diamagnetic complexes |
Presentation |
| Spectra of free radicals and Lanthanide shift Reagents |
Presentation |
| Magnetic susceptibility measurement |
Conventional |
| Solid state NMR- Wide line NMR |
Conventional |
| Magic Angle spinning and give applications of Magnetic Resonance Imaging. |
Presentation |
| Nuclear Quadrupole Resonance Spectroscopy |
Introduction and Nuclear Quadropole Moment, Electric field gradient and Asymmetry Parameter. |
To cover introduction and nuclear quadrupole moment, electric field gradient and asymmetry parameter; nuclear quadrupole transitions; effect of an external magnetic field; applications- chemical bonding and structure, solid state effects, hydrogen bonding |
Conventional |
4 |
| Nuclear Quadrupole Transitions: Axially symmetric and Non-symmetric Molecules. |
Presentation |
| Effect of an External magnetic field. |
Presentation |
| Applications: Chemical Bonding and Structure, solid state effects, hydrogen bonding |
Conventional |
