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Curriculum | Inorganic Special -IV (Code-09040401) | Fourth Sem | Master of Chemistry

Curriculum

Inorganic Special -IV  (Code-09040401)

S.N/Unit Topic Learning Objectives Teaching guidelines Methodology Time                         (Hours)
1 Study of organometallic compounds Classification of organometallic compounds by bond types viz. covalent, ionic, electron deficient and cluster compounds. To cover Classification of organometallic compounds by bond types viz. covalent, ionic, electron deficient and cluster compounds;types of alkyls and aryls of transition metals; their routes of synthesis; stability and describe decomposition pathways; Organocopper in organic synthesis Conventional 7
Types of alkyls and aryls of transition metals Conventional 8
Their routes of synthesis
Stability and describe decomposition pathways
Organocopper in organic synthesis
       
2 Study of Transition Metal π–Complexes Transition metal π–complexes with unsaturated molecules- alkenes, alkynes, allyl, & dienyl(metallocene) complexes, preparation To cover Transition metal π–complexes with unsaturated molecules- alkenes, alkynes, allyl, & dienyl(metallocene) complexes, preparation; Properties, nature of bonding and structural features; Important reactions related to nucleophilic and electrophilic attack on ligands and organic synthesis Conventional 15
Properties, nature of bonding and structural features Conventional
Important reactions related to nucleophilic and electrophilic attack on ligands and organic synthesis Conventional
3 Study of Compounds containing Transition Metal-Carbon Multiple Bonds Transition metal- carbene complexes: Fischer type and Schrock type carbene complexes To cover Transition metal- carbene complexes: Fischer type and Schrock type carbene complexes; their synthesis; reactions, structure and bonding; Transition metal-carbyne complexes-their synthesis, reactions and structural features Conventional 15
Their synthesis Conventional
Their reactions, structures & bonding Conventional
Transition metal-carbyne complexes-their synthesis, reactions and structural features Conventional
4 Study of Fluxional Organometallic Compounds Fluxionality & dynamic equilibria in compounds such as acyclic alkenes,σ-bonded and π–bonded cyclic alkenes To cover Fluxionality & dynamic equilibria in compounds such as acyclic alkenes,σ-bonded and π–bonded cyclic alkenes; Rotation of ligands on metals, ligand scrambling on metals. Conventional/Presentation 7
Rotation of ligands on metals, ligand scrambling on metals.
Study of applications of Transition metal Organometallics as Catalysts Zeigler-Natta polymerization Conventional 8
Homogeneous catalytic hydrogenation To cover Ziegler-Natta polymerization; homogeneous catalytic hydrogenation; alkene hydrogenation-Wilkinson catalyst; oxidation of olefins-Wacker’s process; Hydroformylation of olefins- the oxo process Conventional
Alkene hydrogenation-Wilkinson Catalyst Conventional
Oxidation of olefins-Wacker’s process Conventional
Hydroformylation of olefins – the oxo process Conventional
Admission 2017