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Curriculum | Title: Organic Special -VI (Code-09040415) | Fourth Sem | Master of Chemistry

Curriculum
Title: Organic Special -VI  (Code-09040415)

S.no. Topic Learning Objectives Teaching guidelines Methodology Time
1 n-Butyllithium and Grignard reagent Students should understand the action of organometallic compounds to cover the emcahnicm and chemical action of organometallic copounds on organic reaction 1. Lecture,                    2. seminar                    3. Group discussion       4. Assignment               5. Evaluation 10
Organo chromium(III) compounds and Dialkyl copper lithium
Pentacarbonyl iron and Tetracarbonyl nickel
octacarbonyl dicobalt and Alkene Palladium (II) complexes
Wilkinsons catalyst and Methyl triisopropoxy titanium
Tri-n-butyl tin hydride and Trimethyl silyl iodide, Diborane.
2 DCCI and 1,3-dithianes Stdents should understand how different chemicals reacts specifically to give specific type of product To cover the action of different chemicals like-DCC, dithian, dizomethans, Cu2Cl2KSY, NBS, Mont-K-10, and PTC 1. Lecture,                    2. seminar                    3. Group discussion       4. Assignment               5. Evaluation 8
Polyphosphoric acid and diazomethane
Ethyldiazoacetate and Boron Trifluoride,
Trifluoro acetic acid and cuprous chloride,
N-bromosuccinamide,Mont- K-10, and KSF (clays)
Phase Transfer catalysts.
3 Oxidation: Students should understand which type of oxidating or reducing agents can be used to give desired product To cover the oxidative raection of Pb(OAc)4, OsO4, KMnO4, O3, CrO3, Thallium nitrate, Periodic acid etc and reducing reaction of LiAlH4, NaBH4,NaNH2, Zn dust, Liq NH3 1. Lecture,                    2. seminar                    3. Group discussion       4. Assignment               5. Evaluation 12
 Leadtetraacetate and osmium tetraoxide, selenium dioxide and potassium permanganate
Fenton’s reagent and ozone, Perbenzoic acid and periodic acid
chromium oxide and thallium (III) nitrate.
Reduction:
Catalytic hydrogenation, lithium aluminium hydride
sodium borohydride, sodamide and zinc dust, sodium-liquid ammonia
4 General mechanistic considerations – nature of migration, migratory aptitude and  detailed study of Pinacol – pinacolone rerrangement Students should undertand the mechanism of given reaction and should utilise in multistel synthesis To cover the detailed mecanism of Pinacol – pinacolone, Wagner-Meerwein, Demjanov and Benzil-Benzilic acid, Favorskii, Neber and Beckmann, Hofman, Curtius and Schmidt rerrangements and Baeyer-Villiger and Shapiro reaction. 1. Lecture,                    2. seminar                    3. Group discussion       4. Assignment               5. Evaluation 12
General mechanistic considerations – nature of migration, migratory aptitude and  detailed study of Wagner-Meerwein rerrangement
General mechanistic considerations – nature of migration, migratory aptitude and  detailed study of Demjanov and Benzil-Benzilic acid rerrangements
General mechanistic considerations – nature of migration, migratory aptitude and  detailed study of Favorskii rerrangement & Arndt-Eistert synthesis
General mechanistic considerations – nature of migration, migratory aptitude and detailed study of Neber and Beckmann rerrangements
General mechanistic considerations – nature of migration, migratory aptitude and  detailed study of Hofman, Curtius and Schmidt rerrangements
General mechanistic considerations – nature of migration, migratory aptitude and  detailed study of Baeyer-Villiger and Shapiro reaction.
Admission 2017