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Curriculum | Title: Physical Special –IV (Code-09040407) | Fourth Sem | Master of Chemistry

Curriculum

Title: Physical Special –IV (Code-09040407)

S.No

Topic

Learning Objectives

Teaching Guidelines

 Methodology

Hours

 

Unit I

 

 

 

 

1

The maximum intrinsic efficiency, actual efficiency and current – potential relation in an electrochemical energy converter

Students should able to learn maximum intrinsic efficiency, energy convertor

Problem solving on this topic

Presentation/interactive lectures

2 hrs

2

Factors influencing the electrochemical energy conversion, the power output of an electrochemical energy converter

Able to know the factors that influence the electrochemical enegy converter

Discuss and explain

Lecture and internet based learning

1 hrs

3

Electrochemical electricity generators (fuel cells), brief idea about H2-O2, hydrocarbon – air, and natural gas & CO -air fuel cells Understand the generators, fuel celss, types

helps stydents visualize chemistry and improve problem solving skills

Presentation/interactive lectures using audio and video aids

3 hrs

4

Electricity storage: some important quantities in electricity storage (electricity storage density, energy density, power Shall know electricity storage, and important quatities

Lecture should be problem based

presentation/interactive lectures using using smart class

3 hrs

5

Desirable conditions for an ideal strorer ,  storage of electricity using the lead-Acid battery, dry cell, silver-zinc cell and Sodium- Sulfur cell able to know the desirable conditions for ideal storer and tpyes of cells

Discuss and explain

presentation, power point presentation

2 hrs

6

Amperometric titrations determination of activation energy for an irreversible electrode process.

Students be able to know the amperometric titrations, electrode process

Lecture should be problem based

improve learning and grades by presentation, audio visual

2 hrs

 

Unit II

1

Thermal decomposition reactions, Nucleation, Free energy of nucleation, Laws, Classification, Functions and growth of nuclei

Learn to know nucleation, laws, classification and functions

Lecture should be problem based

develop skills and build confidence

2 hrs

2

Kinetic expressions for diffusion controlled, phase boundary controlled and nucleation and growth controlled reactions Students be able to get the expressions for controll the growth reactions Search and investigate the mathematical and conceptual approch

motivate students learning

3 hrs

4

Perfect and imperfect crystals, Intrinsic and extrinsic defects, Point defects, Line and plane defects, Vacancies: Schottky and Frenkel defects,Thermodynamics of Schottky and Frenkel defect formation,Colour centres, non-stoichiometry defects Learn the difference between perfect and imperfect cystals, and defects understand the conceptual idea helps students studying university chemistry books in the library

 2 hrs

5

Classification of solids, Lattice energy, Evaluation of Madelung constant (NaCl), Calculation of repulsive potential exponent: Lattice heat capacity, Einstein and Debye model of lattice heat capacity, Debye T3 law. Able to know classification, lattice energy, model and heat capacity of solids Lecture should be problem based Presentation/interactive lectures PPT, projector

2 hrs

 

Unit III

       

1

Classification of polymers and polymerisation, condensation and addition polymers

Students should able to understand  polymers, class, kinetics, mechanism, and sterochemistry

Lecture should be simple, effective, and then Search and investigate the mathematical and conceptual approch

Presentation/interactive lectures using PPT, Projector, audio and video aids

1 hrs

2

Kinetics of condensation (step-wise) polymerisation

2 hrs

3

Size distribution in linear condensation polymers, molecular size control, degree of polymerization

4 hrs

4

Mechanism of vinyl radical polymerisation, molecular weight and its determination, effect of temperature and pressure on chain polymerisation

3 hrs

5

Stereochemistry of polymer chain & stereo regular polymerisation, Ionic polymerisation (similarities and contrast)

2 hrs

6

Kinetics of cationic, anionic polymerisation, kinetics of copolymerisation, criteria for polymer solubility

Able to know cationic, anionic, kinetics, determination of molecular mass of polymers

Lecture should be problem based

presentation/interactive lectures using personal response

2 hrs

7

Mass number and Mass average molecular weight,

2 hrs

8

Determination of molecular weight of  polymers by osmometry, viscometry, light scattering and sedimentation method.

2 hrs

 

Unit IV

     

1

Thermodynamics of biopolymer solutions, Entropy of mixing & liquid state model along with limitation, Free volume theory, Heat and free energy of mixing

Able to biopolymers, entrophy, theory and limitations

Lecture should be problem based

presentation/interactive lectures

1 hrs

2 hrs

2

Osmotic pressure membrane equilibrium, Muscular contraction and energy generation in mechanochemical system, Evaluation of size, shape, molecular weight and extent of hydration of biopolymers by various experimental techniques

Understands the osmotic pressure, shape, molecular weight,and various experiments

Discuss and explain

develop skills and build confidence

2 hrs

1 hrs

3

Sedimentation equilibrium, Hydrodynamic methods,Diffusion, Sedimentation velocity, Viscosity, Electrophoresis and rotational motions

Students should able to know sedimentation equlibrium, methods diffusion

Lecture should be simple, effective, and then Search and investigate the mathematical and conceptual approch

Presentation/interactive lectures using PPT, Projector, audio and video aids

2 hrs

2 hrs

Admission 2017