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Curriculum | Title: Physical special –V (Code-09040408) | Fourth Sem | Master of Chemistry

Curriculum

Title: Physical special –V (Code-09040408)

S.No

Topic

Learning Objectives

Teaching Guidelines

 Methodology

Hours

 

Unit I

 

 

 

 

1

Free energy functions and the partition functions, Calculation of equilibrium constant  using partition function

Students should able to learn maximum intrinsic efficiency, energy convertor

Problem solving on this topic

Presentation/interactive lectures

2 hrs

2

Bose-Einstein statistics, statistics of photon gas, gas  degeneration, Fermi-Dirac statistics, extreme gas degeneration

Able to know the factors that influence the electrochemical enegy converter

Discuss and explain

Lecture and internet based learning

1 hrs

3

Energy of Bosons & Fermi particles, specific heat of electron gas, , Thermionic emission Understand the generators, fuel celss, types

helps stydents visualize chemistry and improve problem solving skills

Presentation/interactive lectures using audio and video aids

3 hrs

4

Comparison of Maxwell-Boltsmann, Bose-Einstein and  Fermi-Dirac statistics. Shall know electricity storage, and important quatities

Lecture should be problem based

presentation/interactive lectures using using smart class

3 hrs

 

Unit II

1

General theory of non-equilibrium processes, entropy production and entropy flow, thermodynamic criteria for non-equilibrium states

Learn to know nucleation, laws, classification and functions

Lecture should be problem based

develop skills and build confidence

2 hrs

2

3

entropy production in heat flow, mass flow, electric current, chemical reactions Students be able to get the expressions for controll the growth reactions Search and investigate the mathematical and conceptual approch

motivate students learning

3 hrs

4

Saxen’s relation, Onsager’s reciprocity relation, electro kinetic phenomenon Learn the difference between perfect and imperfect cystals, and defects understand the conceptual idea helps students studying university chemistry books in the library

 2 hrs

5

Theory of fluctuation, energy fluctuations in the canonical ensemble, distribution function and fluctuations, fluctuations of density and energy.

Able to know classification, lattice energy, model and heat capacity of solids

Lecture should be problem based

Presentation/interactive lectures PPT, projector

2 hrs

6

2 hrs

 

Unit III

     

1

Angular momentum, angular momentum operators in cartesian coordinates, Eigen function & eigen values, commutation relation between angular momentum operators ( Lx,Ly , Lz , L2  ),

Students should able to understand  angular momentum, commutation, and relation

Search and investigate the mathematical and conceptual approch

Presentation/interactive lectures using PPT, Projector, audio and video aids

3 hrs

3

Total orbital angular momentum and spin angular momentum, Commutation relation between components of total  orbital angular momentum and spin angular momentum

Able to know the mathematical derivation of total angular mementum, and the relation with spin angular momentum

Discuss and explain, Lecture should be problem based

presentation/interactive lectures

3 hrs

5

Ladder operators, commutators of [L2 , L+   ] and [L2  ,L-  ] Application of ladder operators to an eigen function of Lz

Students should know the Ladder operators, and applications to find eigen functions

Lecture should be simple, effective

presentation/ interative lecture using board and marker

3 hrs

 

Unit IV

     

1

Huckel molecular orbital (HMO) theory of llinear and cyclic conjugated systems

Students must know HMO theory for linear and conjugated systems

Lecture should be  conceptual and mathematical based presentation/interactive lectures

3 hrs

2

Applications of HMO theory to,(i) set up and solve Huckel determent equation, (ii) calculate resonance energy; (iii) wave functions for  molecular orbitals

Able to apply the HMO to calculated the RE, wave functions of MO

Lecture should be conceptual and problem based

lecture and internet based learning, using PPT

3 hrs

6

Molecular diagrams for the following, (a) Ethylene molecule (b) Allyl system (Allyl radical and the related cation and anion), (c) Butadiene; (d) Cyclobutadiene (e) Cyclopropenyl system (cyclopropenyl radical and the related cation and anion

Able to use MOT to different systems

discuss and explain lecture should be problem based

Presentation/interactive lectures using PPT, Projector, audio and video aids

2 hrs