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Inorganic Special I (Code 09040301) | Third Sem | Master of Chemistry

Inorganic Special -I  (Code-09040301)

S.N Topic  Domain Time                         (Hours)
  Study of Vibrational Spectroscopy   15
1 Symmetry and shapes of AB2, AB3,AB4.AB5 and AB6 Must know
Modes of bonding of ambidentate ligands- Ethylenediamine and diketonate complexes Must know
Application of resonance Raman Spectroscopy particularly for the study of active sites of metalloproteins as myoglobin and haemoglobin Must know
2 Study of Electron Spin Resonance Spectroscopy
The Principle Must know 15
Presentation of the spectrum Must know
Hyperfine coupling and hyperfine splitting in various structures Must know
Factors affecting magnitude of g Must know
Zero field splitting and Kramer’s degeneracy Must know
Applications to transition metal complexes having one and more than one unpaired electron Must know
Applications to inorganic free radicals Must know
Study of electron exchange reactions. Nice to know
  Study of Moessbauer Spectroscopy
3 Basic principles Must know 8
Spectral display and  isomer shift Must know
Factors affecting the magnitude of isomer shift Must know
Quadrupole and magnetic hyperfine interaction Must know
The applications for techniques to  study  bonding and structure of Fe2+, Fe3+ ;  Sn2+ and Sn4+ compounds. Must know
Detection of oxidation states and  nature of M-L bond. Must know
Study of Mass Spectroscopy  
Principle and  representation Must know 7
Interaction of molecule with high energy electrons Must know
Interpretation of mass spectrum and  effect of isotopes on appearance of mass spectrum. Must know
Applications- finger print application,molelcular weight determination Must know
Heat of sublimation of high melting solids. Nice to know
  Study of Nuclear Magnetic Resonance Spectroscopy
4 Chemical shifts and coupling constants of 19F and 31P NMR spectra Must know 7
19F Spectra of fluoroacetone,  1-bromo-1-Fluoroethane, dimethyl phosphorus trifluoride and bromine pentafluoride Must know
31P spectra of HPF2 HPO(OH)2 H2 PO(OH), cis- Pt(Pet3)2 Cl2 Must know
31P NMR for structural determination of Complexes with phosphorus ligands.E50 Nice to know
Spectra of Paramagnetic Materials  
Contact shift, its origin and application Must know 4
Pseudo contact shift of  Diamagnetic complexes Must know
Spectra of free radicals and  Lanthanide shift Reagents Must know
Magnetic susceptibility measurement Must know
Solid state NMR- Wide line NMR Must know
Magic Angle spinning and give applications of Magnetic Resonance Imaging. Nice to know
Nuclear Quadrupole  Resonance Spectroscopy  
Introduction and  Nuclear Quadropole Moment, Electric field gradient and Asymmetry Parameter. Must know 4
Nuclear Quadrupole Transitions: Axially symmetric and Non-symmetric Molecules. Must know
Effect of an External magnetic field. Nice to know
Applications: Chemical Bonding and Structure, solid state effects, hydrogen bonding Nice to know

Books Recommended:  

 
1. Vibrational Spectroscopy by D.N. Sathyanarayana
2. Introduction to Magnetic Resonance Spectroscopy by ESR, NMR, NQR by D.N. Sathyanarayana
3. Physical methods in Inorganic chemistry by Russel S. Drago
4. Infrared and Raman spectra of Inorganic and coordination Compounds by K. Nakamoto
5. Inorganic infrared and Raman spectra by S.D. Ross