Paper I : (Theory) Physical Chemistry
Code;09010108
S. No / Section | Topic | Domain | Hours |
A
|
Gaseous States
1. Maxwell’s distribution of velocities and energies (derivation excluded) 2. Calculation of root mean square velocity, average velocity and most probable velocity. 3. Collision diameter, collision number, collision frequency and mean free path. 4. Deviation of Real gases for ideal behaviour. 5. Derivation of Vander Waal’s Equation of State, its application in the calculation of Boyle’s temperature (compression factor) 6. Explanation of behaviour of real gases using Vander Waal’s equation |
Must Know | 12 |
B
|
Critical Phenomenon
1. Critical temperature, Critical pressure, critical volume and their determination. 2. PV isotherms of real gases, continuity of states, the isotherms of Vander Waal’s equation, relationship between critical constants and Vander Waal”s constants. 3. Critical compressibility factor. The Law of corresponding states. Lequifaction of gases |
Must Know | 10 |
C
|
Liquid State
1. Structure of liquids. 2. Properties of liquids – surface tension, 3. Viscosity 4. Vapour pressure and 5. Optical rotations and their determination |
Nice to know | 14 |
Books :
- Chemistry for Degree Students ( B. Sc I) by Dr. R.L. Madan , S . Chand
- Essential of Physical Chemistry by Arun Bhal , B.S. Bhal , G.D. Tuli
- Physical Chemistry, Borrow G.M. (2007) Tata McGraw-Hill
- Physical Chemistry, Castellian G.W(2004) 4th Edition Narosa