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Syllabus | B.Sc (Non- Medical) | Paper V (Theory) Inorganic Chemistry Code 09010507

Paper V (Theory) Inorganic Chemistry Code 09010507

S.No. Topic Domain Hours as
per MCI
1 Metal-ligand Bonding in Transition Metal-Complexes
1. Limitations of valence  bond theory
2. Crystal-field theory
3. Crystal field splitting in   octahedral, tetrahedral and square planar complexes, 4.Factors affecting the crystal-field parameters.
 

Must Know

 

Desirable to Know

 

5

2. Thermodynamic and Kinetic Aspects of Metal Complexes
1. A brief outline of thermodynamic stability of metal complexes
2. factors affecting the stability, substitution reactions of  square-planar-complexes of Pt(II)
 

 

Must Know

 

8

3. Magnetic Properties of Transition Metal Complexes:
1. Types of magnetic behavior
2. Methods of determining magnetic susceptibility, spin-only formula.
3. L-S coupling, correlation of s  and eff values,
4. Orbital contribution to magnetic moments,
5. Application of magnetic moment data for 3d- metal complexes.
.
 

 

Must Know

 

8

3. Electron Spectra of Transition Metal Complexes
1. Types of electronic transitions
2. Selection rules for d-d transitions
3. Spectroscopic ground states, spectro chemical series.
4. Orgel-energy level diagram for d1 and d9 states, discussion of the electronic spectrum of[Ti(H2O)6]3+complexion.
 

Must Know

 

8

Books :

  1. Chemistry for Degree Students ( B. Sc III)  By Dr. R.L. Madan , S . Chand
  2. Concise Inorganic Chemistry , J.D Lee (Latest Edition) E.L.B.S.
  3. University Chemistry 3rd Edition by  B H Mahan, Narosa
  4. Concepts and Models in Inorganic Chemistry , Douglas , McDanial and Alexanderm, John Wiley
Admission 2017