Title: General Spectroscopy (Code-09040207)
|S.No.||Topic||Domain||Hours as per UGC|
|1||Unit -1 Interaction of electromagnetic radiation with matter, regions of the Spectrum the width and intensity of spectral transitions. Resolving power.||Must Know||10|
|The rotation of molecules, rotational spectra of diatomic molecules, the spectrum of non rigid rotator, the effect of isotopic substitutions rotational spectra of linear and symmetric top polyatomic molecules.|
|The vibrating diatomic molecule; simple harmonic vibrations, anharmonicity of vibrations, the diatomic vibrating rotator, the interaction of rotations and vibrations the vibrations of polyatomic molecules, analysis by infrared technique.||Nice to know|
|Electronic spectra of diatomic molecules, vibrational course structure, and rotational fine structure of electronic band. The Frank- Condon principle, intensity of vibrational-electronic band, dissociation energy, the Fortrat diagram.||Must know|
|2||Unit -2 Energy levels in diatomic molecules, introduction to electronic transition,||Must Know||8|
|Assignment of transitions, Spectra of transition metal complexes, Orgel diagrams.|
|Applications of spin-spin coupling to structure alignment of inorganic compounds,|
|evaluation of reaction rates of fast exchange reactions.||Desirable to know|
|The double resonance technique. Application of infra-red spectroscopy to the determination of inorganic compounds.|
|3||Unit – 3 Spin active nuclei, chemical shift, shielding and deshielding, internal standards, spin-spin coupling, equivalent and non- Equivalent Protons,||Must Know||12|
|effect of changing solvents and hydrogen bonding on chemical shifts, anisotropic effect.|
|Principles and Applications of UV, IR and NMR Spectra in the structure elucidation of Organic Compounds.||Desirable to know|
- Drago, R.S. Physical Methods in Inorganic Chemistry.
- Nakamoto, K. Infrared Spectra of Inorganic and Coordination Compound.
- Banwel, C.N. Fundamentals of Molecules Spectroscopy.
- Sathyanarayana, D.N. Introduction to Magnetic Resonance Spectroscopy ESR, NMR, NRR.
- Kalsi P.S. , Spectroscopy of Organic Compounds