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Title: Physical Chemistry I (Code 09040307) | Third Sem | Master of Chemistry

Title: Physical Chemistry-I  (Code-09040307)

S.No Topic Domain Hours
  Unit I    
1 Thermodynamics of electrified interfaces Nice to know 1 hrs
2 Electrocapillary thermodynamics, non-polarizable interface and thermodynamic equilibrium Nice to know 2 hrs
3 Fundamental thermodynamic equation of polarizable interfaces Must Know 3 hrs
4 Determination of excess charge density on the electrode, electrical capacitance and surface excess of the interface Must Know 2 hrs
5 Potential of zero charge, Helmholtz-Perrin model, Gouy – Chapman model and Stern model of electrified interfaces. Nice to know 2 hrs
  Unit II    
1 The thermal dismantling of an ionic lattice, characteristics of ionic liquids Must Know 2 hrs
2 The fundamental problems in the study of pure liquid electrolytes, models of simple ionic liquids Good To Know 3 hrs
3 Lattice oriented models (the vacancy model, the hole model Nice to know 3 hrs
4 Quantification of the hole model, the Furth approach to the work of hole formation, distribution function for the sizes of the holes and the average size of a hole    
5 Rate of charge- transfer reactions under zero fields, under the influence of an electric field, Must Know 3 hrs
6 The equilibrium exchange current density, the non-equilibrium drift-current density (Butler – Volmer) equation Good To Know 2 hrs
7 Some general and special cases of Butler- Volmer equation, the high-field and low-field approximations, physical meaning of the symmetry factor Nice to know 2 hrs
8 Preliminary to a second theory , a simple picture of the symmetry factor and its dependence on overpotential.  Polarizable and non-polarizable interfaces Must Know 2 hrs
  Unit III    
1 Surface tension, capillary action, pressure difference across curved surface (Leplace equation) Must Know 2 hrs
2 Gibb’s adsorption equation and its applications Good To Know 3 hrs
3 Determination of BET equation and its application for the determination of surface area Nice to know 4 hrs
4 Surface active agents and their classification, concept of micelles, critical micelle concentration (cmc) Good To Know 3 hrs
5 Determination of cmc by conductivity and surface tension methods Must Know 2 hrs
6 factors affecting cmc, counter – ion binding to micelles, thermodynamics of micellization Nice to know 3 hrs
  Unit IV    
1 Study of fast reactions Good To Know 2 hrs
2 Flow methods, Relaxation method, Flash photolysis and    shock tube method. Nice to know 2 hrs
3 Theories of unimolecular reactions Must Know 2 hrs
4 Lindemann’s  theory, Hinshelwoods treatment, R.R.K. and R.R.K.M. theories    
5 The theory of absolute reaction rates, Must Know 2 hrs
6 Potential energy surfaces, activation energies Good To Know 3 hrs
7 London-Eyring – Polanyi method for the calculation of energy of activation Nice to know 4 hrs

Books Recommended:
1. Bockris, J.O.M. and A.K.N. Reddy. Modern Electrochemistry Vol.1& 2.
1. Laidler, K.J. Chemical Kinetics.
2. Frost, A. and G.Pearson. Kinetics and Mechanism of Reaction Rates.
3. Laidler, K.J., H. Eyring and S. Glasstone. Theories of Reaction Rates.
4. Glasstone, S. Electrochemistry.

Admission 2017