1800 102 5661 info@sgtuniversity.org

Title: Physical special –V (Code-09040408) | Fourth Sem | Master of Chemistry

Title: Physical special –V (Code-09040408)

S.No Topic Domain Hours
  Unit I    
1 Free energy functions and the partition functions Must Know 2 hrs
2 Calculation of equilibrium constant  using partition function Must Know 1 hrs
3 Bose-Einstein statistics, statistics of photon gas, gas  degeneration Good To Know 3 hrs
4 Fermi-Dirac statistics, extreme gas degeneration Good To Know 3 hrs
5 Energy of Bosons & Fermi particles, specific heat of electron gas, , Thermionic emission Nice to know 2 hrs
6 Comparison of Maxwell-Boltsmann, Bose-Einstein and  Fermi-Dirac statistics. Must Know 2 hrs
  Unit II
1 General theory of non-equilibrium processes, entropy production and entropy flow Must Know 2 hrs
2 thermodynamic criteria for non-equilibrium states Nice to know
3 entropy production in heat flow, mass flow, electric current, chemical reactions Must Know 3 hrs
4 Saxen’s relation, Onsager’s reciprocity relation, electro kinetic phenomenon Nice to know  2 hrs
5 Theory of fluctuation, energy fluctuations in the canonical ensemble Must Know 2 hrs
6 distribution function and fluctuations, fluctuations of density and energy. Good To Know 2 hrs
  Unit III
1 Angular momentum, angular momentum operators in cartesian coordinates Nice to know 2 hrs
2 Eigen function & eigen values, commutation relation between angular momentum operators ( Lx,Ly , Lz , L2  ), Good To Know 2 hrs
3 Total orbital angular momentum and spin angular momentum
4 Commutation relation between components of total  orbital angular momentum and spin angular momentum Nice to know 1 hrs
5 Ladder operators, commutators of [L2 , L+   ] and [L2  ,L-  ] Good To Know 2 hrs
6 Application of ladder operators to an eigen function of Lz Must Know 4 hrs
  Unit IV
1 Huckel molecular orbital (HMO) theory of llinear and cyclic conjugated systems Must Know 2 hrs
2 Applications of HMO theory to Nice to know 2 hrs
3 (i) set up and solve Huckel determent equation Nice to know 2 hrs
4 (ii) calculate resonance energy; Must Know 2 hrs
5 (iii) wave functions for  molecular orbitals
6 Molecular diagrams for the following
7 (a) Ethylene molecule (b) Allyl system (Allyl radical and the related cation and anion) Must Know 1 hrs
8 (c) Butadiene; (d) Cyclobutadiene (e) Cyclopropenyl system (cyclopropenyl radical and the related cation and anion Nice to know 1 hrs

 

Books Recommended:
1. Prigogine, I. Non-Equilibrium Thermodynamics.
2     Kalidas, C.  Non-Equilibrium Thermodynamics.

Admission 2017