Title: Physical special –V (Code-09040408)
S.No | Topic | Domain | Hours |
Unit I | |||
1 | Free energy functions and the partition functions | Must Know | 2 hrs |
2 | Calculation of equilibrium constant using partition function | Must Know | 1 hrs |
3 | Bose-Einstein statistics, statistics of photon gas, gas degeneration | Good To Know | 3 hrs |
4 | Fermi-Dirac statistics, extreme gas degeneration | Good To Know | 3 hrs |
5 | Energy of Bosons & Fermi particles, specific heat of electron gas, , Thermionic emission | Nice to know | 2 hrs |
6 | Comparison of Maxwell-Boltsmann, Bose-Einstein and Fermi-Dirac statistics. | Must Know | 2 hrs |
Unit II | |||
1 | General theory of non-equilibrium processes, entropy production and entropy flow | Must Know | 2 hrs |
2 | thermodynamic criteria for non-equilibrium states | Nice to know | |
3 | entropy production in heat flow, mass flow, electric current, chemical reactions | Must Know | 3 hrs |
4 | Saxen’s relation, Onsager’s reciprocity relation, electro kinetic phenomenon | Nice to know | 2 hrs |
5 | Theory of fluctuation, energy fluctuations in the canonical ensemble | Must Know | 2 hrs |
6 | distribution function and fluctuations, fluctuations of density and energy. | Good To Know | 2 hrs |
Unit III | |||
1 | Angular momentum, angular momentum operators in cartesian coordinates | Nice to know | 2 hrs |
2 | Eigen function & eigen values, commutation relation between angular momentum operators ( L_{x},L_{y} , L_{z} , L^{2} ), | Good To Know | 2 hrs |
3 | Total orbital angular momentum and spin angular momentum | ||
4 | Commutation relation between components of total orbital angular momentum and spin angular momentum | Nice to know | 1 hrs |
5 | Ladder operators, commutators of [L2 , L+ ] and [L2 ,L- ] | Good To Know | 2 hrs |
6 | Application of ladder operators to an eigen function of Lz | Must Know | 4 hrs |
Unit IV | |||
1 | Huckel molecular orbital (HMO) theory of llinear and cyclic conjugated systems | Must Know | 2 hrs |
2 | Applications of HMO theory to | Nice to know | 2 hrs |
3 | (i) set up and solve Huckel determent equation | Nice to know | 2 hrs |
4 | (ii) calculate resonance energy; | Must Know | 2 hrs |
5 | (iii) wave functions for molecular orbitals | ||
6 | Molecular diagrams for the following | ||
7 | (a) Ethylene molecule (b) Allyl system (Allyl radical and the related cation and anion) | Must Know | 1 hrs |
8 | (c) Butadiene; (d) Cyclobutadiene (e) Cyclopropenyl system (cyclopropenyl radical and the related cation and anion | Nice to know | 1 hrs |
Books Recommended:
1. Prigogine, I. Non-Equilibrium Thermodynamics.
2 Kalidas, C. Non-Equilibrium Thermodynamics.